Dynamics of Chemical and Biochemical Systems - Bewerkingsoverzicht

Nickskeuh: /* 8 juni 2018 - voormiddag */

2018-06-08T13:18:05Z

8 juni 2018 - voormiddag

← Oudere versie		Versie van 8 jun 2018 15:18
Regel 11:		Regel 11:
	===8 juni 2018 - voormiddag===		===8 juni 2018 - voormiddag===
	# Gegeven de Master Equation of Fluctuation Theory, voor zowel P(delta P, delta S) als P(delta T, delta V). Wat kan je hieruit besluiten over fluctuaties in het algemeen. En meer specifiek over isotherme compressie.		# Gegeven de Master Equation of Fluctuation Theory, voor zowel P(delta P, delta S) als P(delta T, delta V). Wat kan je hieruit besluiten over fluctuaties in het algemeen. En meer specifiek over isotherme compressie.
	# Reactie A+C <-> B+C. Leidt de relaxatieformule af. Welke kinetische waarden kunnen hieruit gehaal worden. Welke condities zijn nodig. Wat kan er zorgen voor perturbatie. En geef de verschillende tijdsprofielen.		# Reactie A+C <-> B+C met C als katalysator. Leidt de relaxatieformule af. Welke kinetische waarden kunnen hieruit gehaal worden. Welke condities zijn nodig. Wat kan er zorgen voor perturbatie. En geef de verschillende tijdsprofielen.

	===24 augustus 2017 - voormiddag===		===24 augustus 2017 - voormiddag===

Nickskeuh: /* Examenvragen */

2018-06-08T13:17:23Z

Examenvragen

← Oudere versie		Versie van 8 jun 2018 15:17
Regel 5:		Regel 5:

	==Examenvragen==		==Examenvragen==
			===8 juni 2018 - Namiddag===
			# Gegeven de Master Equation of Fluctuation Theory, voor zowel P(delta P, delta S) als P(delta T, delta V). Wat kan je hieruit besluiten over fluctuaties in het algemeen. En dan nog gegeven U=RT en dat Cv= T (δU/δT), wat kan hier nog mee besluiten.
			# Reactie A+B <-> C+D. Leidt de relaxatieformule af. Welke kinetische waarden kunnen hieruit gehaal worden. Welke condities zijn nodig. Wat kan er zorgen voor perturbatie. En geef de verschillende tijdsprofielen.

			===8 juni 2018 - voormiddag===
			# Gegeven de Master Equation of Fluctuation Theory, voor zowel P(delta P, delta S) als P(delta T, delta V). Wat kan je hieruit besluiten over fluctuaties in het algemeen. En meer specifiek over isotherme compressie.
			# Reactie A+C <-> B+C. Leidt de relaxatieformule af. Welke kinetische waarden kunnen hieruit gehaal worden. Welke condities zijn nodig. Wat kan er zorgen voor perturbatie. En geef de verschillende tijdsprofielen.

	===24 augustus 2017 - voormiddag===		===24 augustus 2017 - voormiddag===
	# Prove that the stability condition in terms of increase in entropy can be related to a minimun in "energy". Relate this to the presence of fluctuations around this minimun. Extra question during oral: You have 2 graphs from the course text and he asks which one is more fundamental: G or S?		# Prove that the stability condition in terms of increase in entropy can be related to a minimun in "energy". Relate this to the presence of fluctuations around this minimun. Extra question during oral: You have 2 graphs from the course text and he asks which one is more fundamental: G or S?
	# What's the relation between the Fick's law of diffusion and the Langevin equation for the diffusion coëfficiënt in terms of temperature and friction? Extra question during oral: What is Rh (hydrodynamic radius)?		# What's the relation between the Fick's law of diffusion and the Langevin equation for the diffusion coëfficiënt in terms of temperature and friction? Extra question during oral: What is Rh (hydrodynamic radius)?
	# Give a simple graphic example of the relation between statistical thermodyamics, the partition function and the chemical equilibrium constant. Give an example of products and reagents for which your simple example is valid. (this is about the first 2 lessons at the start of the semester)		# Give a simple graphic example of the relation between statistical thermodyamics, the partition function and the chemical equilibrium constant. Give an example of products and reagents for which your simple example is valid. (this is about the first 2 lessons at the start of the semester)

	===9 juni 2017 - namiddag===		===9 juni 2017 - namiddag===
	# Describe the nature and relevance of fluctuations given that it can derived from the Master Equation of Fluctuation Theory that: [[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|center\|alternatieve tekst]]		# Describe the nature and relevance of fluctuations given that it can derived from the Master Equation of Fluctuation Theory that: [[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|center\|alternatieve tekst]]

Xana.schoubben: /* Examenvragen */

2017-08-24T10:17:19Z

Examenvragen

← Oudere versie		Versie van 24 aug 2017 12:17
Regel 6:		Regel 6:
	==Examenvragen==		==Examenvragen==
	===24 augustus 2017 - voormiddag===		===24 augustus 2017 - voormiddag===
	# Prove that the stability condition in terms of increase in entropy can be related to a minimun in "energy". Relate this to the presence of fluctuations around this minimun.		# Prove that the stability condition in terms of increase in entropy can be related to a minimun in "energy". Relate this to the presence of fluctuations around this minimun. Extra question during oral: You have 2 graphs from the course text and he asks which one is more fundamental: G or S?
	Extra question during oral: You have 2 graphs from the course text and he asks which one is more fundamental: G or S?		# What's the relation between the Fick's law of diffusion and the Langevin equation for the diffusion coëfficiënt in terms of temperature and friction? Extra question during oral: What is Rh (hydrodynamic radius)?
	# What's the relation between the Fick's law of diffusion and the Langevin equation for the diffusion coëfficiënt in terms of temperature and friction?		# Give a simple graphic example of the relation between statistical thermodyamics, the partition function and the chemical equilibrium constant. Give an example of products and reagents for which your simple example is valid. (this is about the first 2 lessons at the start of the semester)
	Extra question during oral: What is Rh (hydrodynamic radius)?
	# Give a simple graphic example of the relation between statistical thermodyamics, the partition function and the chemical equilibrium constant. Give an example of products and reagents for which your simple example is valid.
	(this is about the first 2 lessons at the start of the semester)
	===9 juni 2017 - namiddag===		===9 juni 2017 - namiddag===
	# Describe the nature and relevance of fluctuations given that it can derived from the Master Equation of Fluctuation Theory that: [[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|center\|alternatieve tekst]]		# Describe the nature and relevance of fluctuations given that it can derived from the Master Equation of Fluctuation Theory that: [[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|center\|alternatieve tekst]]

Xana.schoubben: /* Examenvragen */

2017-08-24T10:16:49Z

Examenvragen

← Oudere versie		Versie van 24 aug 2017 12:16
Regel 7:		Regel 7:
	===24 augustus 2017 - voormiddag===		===24 augustus 2017 - voormiddag===
	# Prove that the stability condition in terms of increase in entropy can be related to a minimun in "energy". Relate this to the presence of fluctuations around this minimun.		# Prove that the stability condition in terms of increase in entropy can be related to a minimun in "energy". Relate this to the presence of fluctuations around this minimun.
	Extra question during oral: You have 2 graphs from the course text and he asks which one is more fundamental: G or S?		Extra question during oral: You have 2 graphs from the course text and he asks which one is more fundamental: G or S?
	# What's the relation between the Fick's law of diffusion and the Langevin equation for the diffusion coëfficiënt in terms of temperature and friction?		# What's the relation between the Fick's law of diffusion and the Langevin equation for the diffusion coëfficiënt in terms of temperature and friction?
	Extra question during oral: What is Rh (hydrodynamic radius)?		Extra question during oral: What is Rh (hydrodynamic radius)?
	# Give a simple graphic example of the relation between statistical thermodyamics, the partition function and the chemical equilibrium constant. Give an example of products and reagents for which your simple example is valid.		# Give a simple graphic example of the relation between statistical thermodyamics, the partition function and the chemical equilibrium constant. Give an example of products and reagents for which your simple example is valid.
	(this is about the first 2 lessons at the start of the semester)		(this is about the first 2 lessons at the start of the semester)
	===9 juni 2017 - namiddag===		===9 juni 2017 - namiddag===
	# Describe the nature and relevance of fluctuations given that it can derived from the Master Equation of Fluctuation Theory that: [[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|center\|alternatieve tekst]]		# Describe the nature and relevance of fluctuations given that it can derived from the Master Equation of Fluctuation Theory that: [[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|center\|alternatieve tekst]]

Xana.schoubben: /* Examenvragen */

2017-08-24T10:16:01Z

Examenvragen

← Oudere versie		Versie van 24 aug 2017 12:16
Regel 5:		Regel 5:

	==Examenvragen==		==Examenvragen==
			===24 augustus 2017 - voormiddag===
			# Prove that the stability condition in terms of increase in entropy can be related to a minimun in "energy". Relate this to the presence of fluctuations around this minimun.
			Extra question during oral: You have 2 graphs from the course text and he asks which one is more fundamental: G or S?
			# What's the relation between the Fick's law of diffusion and the Langevin equation for the diffusion coëfficiënt in terms of temperature and friction?
			Extra question during oral: What is Rh (hydrodynamic radius)?
			# Give a simple graphic example of the relation between statistical thermodyamics, the partition function and the chemical equilibrium constant. Give an example of products and reagents for which your simple example is valid.
			(this is about the first 2 lessons at the start of the semester)
	===9 juni 2017 - namiddag===		===9 juni 2017 - namiddag===
	# Describe the nature and relevance of fluctuations given that it can derived from the Master Equation of Fluctuation Theory that: [[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|center\|alternatieve tekst]]		# Describe the nature and relevance of fluctuations given that it can derived from the Master Equation of Fluctuation Theory that: [[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|center\|alternatieve tekst]]

Gertsteurs op 9 jun 2017 om 16:30

2017-06-09T16:30:13Z

← Oudere versie		Versie van 9 jun 2017 18:30
Regel 11:		Regel 11:

	===9 juni 2017 - voormiddag===		===9 juni 2017 - voormiddag===
	# Describe the nature and relevance of fluctuations given that it can derived from the Master Equation of Fluctuation Theory that:		# Describe the nature and relevance of fluctuations given that it can derived from the Master Equation of Fluctuation Theory that: [[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|center\|alternatieve tekst]]
	[[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|center\|alternatieve tekst]]
	# Derive the Stokes-Einstein relation starting from the Langevin equation.		# Derive the Stokes-Einstein relation starting from the Langevin equation.
	# Relaxation:		# Relaxation:

Gertsteurs op 9 jun 2017 om 16:30

2017-06-09T16:30:04Z

← Oudere versie		Versie van 9 jun 2017 18:30
Regel 6:		Regel 6:
	==Examenvragen==		==Examenvragen==
	===9 juni 2017 - namiddag===		===9 juni 2017 - namiddag===
	# Describe the nature and relevance of fluctuations given that it can derived from the Master Equation of Fluctuation Theory that:		# Describe the nature and relevance of fluctuations given that it can derived from the Master Equation of Fluctuation Theory that: [[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|center\|alternatieve tekst]]
	[[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|center\|alternatieve tekst]]
	# Prove that for stability conditions in terms of entropy can be related to a minimum in "energy". Relate this to the presence of fluctuations around this minimum.		# Prove that for stability conditions in terms of entropy can be related to a minimum in "energy". Relate this to the presence of fluctuations around this minimum.
	# Prove that linearization is necessary for obtaining the right formulae for relaxation for a reaction A + B <=> C and not for A <=> B. Give the formulae for the relaxation times for both reactions. What is minimally necessary for a good relaxation experiment and what are the optimal conditions?		# Prove that linearization is necessary for obtaining the right formulae for relaxation for a reaction A + B <=> C and not for A <=> B. Give the formulae for the relaxation times for both reactions. What is minimally necessary for a good relaxation experiment and what are the optimal conditions?

Gertsteurs: /* Examenvragen */

2017-06-09T15:13:48Z

Examenvragen

← Oudere versie		Versie van 9 jun 2017 17:13
Regel 6:		Regel 6:
	==Examenvragen==		==Examenvragen==
	===9 juni 2017 - namiddag===		===9 juni 2017 - namiddag===
	# Describe the nature and relevance of fluctuations given that it can derived from the ~~masterequation~~ of ~~fluctuation theory~~ that:		# Describe the nature and relevance of fluctuations given that it can derived from the Master Equation of Fluctuation Theory that:
	[[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|center\|alternatieve tekst]]		[[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|center\|alternatieve tekst]]
	# Prove that for stability conditions in terms of entropy can be related to a minimum in "energy". Relate this to the presence of fluctuations around this minimum.		# Prove that for stability conditions in terms of entropy can be related to a minimum in "energy". Relate this to the presence of fluctuations around this minimum.
	# Prove that linearization is necessary for obtaining the right formulae for relaxation for a reaction A + B <=> C and not for A <=> B. Give the formulae for the relaxation times for both reactions. What is minimally necessary for a good relaxation experiment and what are the optimal conditions?		# Prove that linearization is necessary for obtaining the right formulae for relaxation for a reaction A + B <=> C and not for A <=> B. Give the formulae for the relaxation times for both reactions. What is minimally necessary for a good relaxation experiment and what are the optimal conditions?

			===9 juni 2017 - voormiddag===
			# Describe the nature and relevance of fluctuations given that it can derived from the Master Equation of Fluctuation Theory that:
			[[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|center\|alternatieve tekst]]
			# Derive the Stokes-Einstein relation starting from the Langevin equation.
			# Relaxation:
			## How can one perturbate an equilibrium?
			## Which assumptions does one have to make deriving the relaxation formulae?
			## Derive relaxation formulae for the reactions A + B <=> C + D and A <=> B.
			## What is minimally necessary for a good relaxation experiment?

	===Oude examenvragen===		===Oude examenvragen===

Gertsteurs op 9 jun 2017 om 15:08

2017-06-09T15:08:26Z

← Oudere versie		Versie van 9 jun 2017 17:08
Regel 7:		Regel 7:
	===9 juni 2017 - namiddag===		===9 juni 2017 - namiddag===
	# Describe the nature and relevance of fluctuations given that it can derived from the masterequation of fluctuation theory that:		# Describe the nature and relevance of fluctuations given that it can derived from the masterequation of fluctuation theory that:
	[[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|alternatieve tekst]]		[[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|center\|alternatieve tekst]]
	# Prove that for stability conditions in terms of entropy can be related to a minimum in "energy". Relate this to the presence of fluctuations around this minimum.		# Prove that for stability conditions in terms of entropy can be related to a minimum in "energy". Relate this to the presence of fluctuations around this minimum.
	# Prove that linearization is necessary for obtaining the right formulae for relaxation for a reaction A + B <=> C and not for A <=> B. Give the formulae for the relaxation times for both reactions. What is minimally necessary for a good relaxation experiment and what are the optimal conditions?		# Prove that linearization is necessary for obtaining the right formulae for relaxation for a reaction A + B <=> C and not for A <=> B. Give the formulae for the relaxation times for both reactions. What is minimally necessary for a good relaxation experiment and what are the optimal conditions?

Gertsteurs op 9 jun 2017 om 15:08

2017-06-09T15:08:09Z

← Oudere versie		Versie van 9 jun 2017 17:08
Regel 7:		Regel 7:
	===9 juni 2017 - namiddag===		===9 juni 2017 - namiddag===
	# Describe the nature and relevance of fluctuations given that it can derived from the masterequation of fluctuation theory that:		# Describe the nature and relevance of fluctuations given that it can derived from the masterequation of fluctuation theory that:
	[[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|~~200px~~\|alternatieve tekst]]		[[Bestand:P(dV,dT)_term_of_Master_Eequation_of_fluctuation_theory.PNG\|400px\|alternatieve tekst]]
	# Prove that for stability conditions in terms of entropy can be related to a minimum in "energy". Relate this to the presence of fluctuations around this minimum.		# Prove that for stability conditions in terms of entropy can be related to a minimum in "energy". Relate this to the presence of fluctuations around this minimum.
	# Prove that linearization is necessary for obtaining the right formulae for relaxation for a reaction A + B <=> C and not for A <=> B. Give the formulae for the relaxation times for both reactions. What is minimally necessary for a good relaxation experiment and what are the optimal conditions?		# Prove that linearization is necessary for obtaining the right formulae for relaxation for a reaction A + B <=> C and not for A <=> B. Give the formulae for the relaxation times for both reactions. What is minimally necessary for a good relaxation experiment and what are the optimal conditions?