Advanced Inorganic Chemistry: verschil tussen versies

Versie van 29 jan 2024 18:14

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Write the element abundance equations and the corresponding vector-matrix form for a reaction involving the species NH3, O2, NO, NO2 and H2O. Assume that the initial state of the system consists of NH3 and O2 in the molar ratio 4:7. (Example 2.4 p 24 course text)
The enthalpy changes for the following three reactions, which represent the formation of dilute boric acid solution, the dissolution of crystalline boric oxide and the formation of liquid water respectively, are as follows: (see example 3.7 on p 64 of the course text, it is identical). Find the enthalpy of formation for B2O3 (boric acid) from its elements.
What elements belong to group III? Sc-Y-Lu-Lr or Sc-Y-La-Ac? Give arguments in favor or against for both options.
A phase diagram of CO2 is shown similar to that of water at p 144 course text.
- a) Give the Gibbs phase rule for: the liquid part, the line OA (the line that separates liquid from vapor), and O (the triple point).
- b) Why does the line OA stop at A?
The figure showing fractional crystallisation (Fig 6.30 p 172 course text) is shown. How can two components be seperated using Fractional crystallisation?

What is the mechanism of sensitized lanthanide luminescence? Use a scheme to illustrate this mechanism.
Xenon fluoride reactions
- a) Discuss the synthesis and reactivity of xenon fluorides.
- b) Why is it easier to prepare xenon compounds than argon compounds?
Octahedral crystal field
- a) How do p-orbitals and d-orbitals split in an octahedral crystal field?
- b) Determine the ligand field stabilization energy LFSE for the following octahedral metal complexes (a) d3 (b) high-spin d5 (c) high-spin d6 (d) low-spin d6 (e) d9
Describe the hysteresis loop of a ferromagnetic material.
How do polarizing power and polarizability of ions influence partial covalent bond formation of ionic compounds? What different stages can be observed between a purely ionic bond and a purely covalent bond?

What is the mechanism of sensitized lanthanide luminescence? Use a scheme to illustrate this mechanism.
Xenon fluoride reactions
- a) Discuss the synthesis and reactivity of xenon fluorides.
- b) Why is it easier to prepare xenon compounds than argon compounds?
Determine the ligand field stabilization energy LFSE for the following octahedral metal complexes (a) d3 (b) high-spin d5 (c) high-spin d6 (d) low-spin d6 (e) d9
Give 5 examples that illustrate the anomalous chemical behavior of lithium compared to the other alkali metals.
What are the main later developments of the periodic system after Mendeleev’s contributions in 1869–1870?

Periodiek systeem
- a) Periodic trends in MV, density, IE en electronegativiteit
- b) Bespreek La vs Lu in IIIb
Lanthanide-contractie
- a)Trend in ion en atoomradius van lanthaniden
- b) Waarom 4d en 5d metalen gelijkaardige eigenschappen hebben
Solvents
- a) Manieren om non-aqueous solvent op te delen (protisch vs aprotisch - donor vs acceptor)
- b) wat zijn donor- en acceptor solvents?
- c) Hoe geeft men donorsterkte kwantitatief weer?
d-blok metalen
- a) Jahn Teller-effect
- b) Waarom d3 en d8 uitgesproken octahedrisch zijn
CT
- a) Wat zijn charge transfer bands?
- b) Vergelijk LMCT en MLCT
- c) welke d-metaal-complexen vertonen CT-bands?
- d) Hoe kan je CT-bands waarnemen?
- e) Welke lanthaniden vertonen CT en waarom?

@@ Regel 9: / Regel 9: @@
 #What elements belong to group III? Sc-Y-Lu-Lr or Sc-Y-La-Ac? Give arguments in favor or against for both options.
 #A phase diagram of CO2 is shown similar to that of water at p 144 course text.
-##a) Give the Gibbs phase rule for: the liquid part, the line OA (the line that separates liquid from vapor), and O (the triple point).
+#*a) Give the Gibbs phase rule for: the liquid part, the line OA (the line that separates liquid from vapor), and O (the triple point).
-##b) Why does the line OA stop at A?
+#*b) Why does the line OA stop at A?
 #The figure showing fractional crystallisation (Fig 6.30 p 172 course text) is shown. How can two components be seperated using Fractional crystallisation?